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About this image Short Description: M3rbots, clur rsYtocltr - 'r. R' t CX tC". Partkuto will tc time! See our other membership options. Search articles by author Harry Adams.

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Already a Premium member? There are two essentially similar independent molecules within the asymmetric unit.

For reproduction qc101 material from PCCP: If the material has been adapted instead of reproduced from the original RSC publication "Reproduced from" can be substituted with "Adapted from". For reproduction of material from all other RSC journals and books: Back to tab navigation. Go to our Instructions for using Copyright Clearance Center page for details. It began as "The Daily Universal Register" inand became "The Times" on January 1,reporting on events of global importance in political, social, and commercial arenas.
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An important feature of the formation of this molecule is a facile migration reaction of the alkyl chain to an isonitrile ligand. Gist, and r F1ti. Lz li1o9dtfesera Uta I. I I Dinln; Room. The carbene ligand adopts a reverse orientation relative to the cyclopentadienyl ring in that the NMe substituent is orientated below the basal plane away from the cyclopentadienyl ring in contrast to the O substituent in related oxacyclopentylidene complexes. wd101
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Jump to site search. Journal of the Chemical Society, Dalton Transactions. The molecule fails to interconvert from the observed cis configuration to the expected trans complex. You do not have JavaScript enabled. Start your 7-day Free Trial Get Access to this image and everything else on Fold3 Access to over millions of documents. The cyclic carbene ligand and the iodine atom are mutually cis.
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